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Popular Science Monthly
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electrification prior to Volta's experiments, and says in conclusion, after referring to Bennett, 'This last philosopher, as well as Cavallo, appears to think that different bodies have different attractions or capacities for electricity; but the singular hypothesis of electromotion, or a perpetual current of electricity being produced, by the contact of two metals is, I apprehend, peculiar to Volta.' This peculiar theory of Volta's probably never gained many adherents and was necessarily abandoned as soon as the energy relations of the current were considered, but the controversy as to whether the electrical current or the accompanying chemical changes was the primary phenomenon soon became transferred to a quite different field, viz., to the origin of the electrical charges which Bennett had shown resulted from the contact of different metals. Bennett attempted to account for the phenomena which he had observed on the hypothesis that different substances "have a greater or less affinity with the electric fluid," and Cavallo says: 'I am inclined to suspect that different bodies have different capacities for holding the electric fluid.' Volta reaches a similar conclusion after repeating some of Bennett's experiments. In referring to this decision of Volta as to the origin of the electric charge in contact electrification, Ostwald says: 'We stand here at a point where the most prolific error of Electrochemistry begins, the combating of which has from that time on occupied almost the greater part of the scientific work in this field.' The error, from Ostwald's point of view, lies in the assumption that the transference of electricity from the one metal to the other is a primary phenomenon of metallic contact. He, with many others, including some of the most distinguished physicists and chemists of the past century, regard the electrical transference as a secondary phenomenon resulting from the previous oxidation of one of the metals. Thus Lodge, in discussing the opposite electrification of plates of zinc and copper when brought into contact says: 'The effective cause of the whole phenomenon in either case is the greater affinity of oxygen for zinc rather than copper.' The apparent conflict of opinion between those who hold that the different affinities of the metals for oxygen is the cause of the rearrangement of their electrical charges when brought into contact and those who hold with Bennett and Cavallo that the metals in their natural state have different affinities for the electrical fluid must disappear when we recognize that all affinity, and consequently the affinity for oxygen, must be an electrical attraction. If zinc has an affinity for oxygen, it must be because the zinc is either electropositive or electronegative to oxygen. If it has a greater affinity for oxygen than copper has, then the zinc must be either electropositive or electronegative to copper. This being the case, and both being conductors, it is not surprising that some electricity will flow from one to the other when the two metals are brought into contact. Those writers who attribute the oxidation theory of contact electrification to Fabroni apparently overlook the fact that not oxidation, but the weakening of the cohesion of at least one of the metals due to their contact, was the primary phenomenon in Fabroni's theory. When this is remembered, it is seen that the observations of Bennett and Fabroni, instead of furnishing arguments for two conflicting theories, actually serve, as all true scientific observations must, to supplement each other. Thus we now know that cohesion or affinity is an electrical attraction between the atoms or molecules of a body. The only known methods of changing the electrical attraction between two bodies whose distances and directions from other bodies remain constant is by varying the magnitude of their charges or by changing the specific inductive capacity of the medium between them. Bennett observed that when two pieces of different metal in their normal electrical condition are placed in contact, there is a redistribution of the charges of their surface atoms. Fabroni observed under the same conditions a change in the surface cohesion of the two metals. To the present writer this seems the actual sequence of phenomena, viz., a redistribution of the charges of the surface atoms of the metals, a consequent change in surface cohesion and a resultant oxidation of one of the metals. ON CERTAIN RESEMBLANCES BETWEEN THE EARTH AND A BUTTERNUT BY PROFESSOR A, C. LANE TUFTS COLLEGE THE drama of the earth's history consists in the struggle between the forces of uplift and the forces of degradation. The forces of uplift are mainly the outward expression of the inner energy and heat of the earth, whether they be the volcano belching its ashes thousands of meters into the air, or the earthquake, with the attendant crack or fault in the earth's crust, leading to a sudden displacement, and sending, far and wide, a death-dealing shock, or those mountain-building actions, which, though they may be as gentle and gradual as might be produced by the breathing of mother earth and the uplifting of her bosom thereby, nevertheless, end in the huge folds of our mountain ranges. Against these, there are always working the forces of degradation--the slow rotting of weathering caused by the direct chemical action of the moist atmosphere or the alternation of hot and cold which crumbles rocks far above the line where rain never falls. Once the rock is rotten and decayed, it yields readily to the forces of degradation, which drag it down--the beating of the rain, the rush of the avalanche or of the landslide, the tumult of the torrent, the quieter action of the muddy river in its lower reaches or the mighty glacier which transfers fine and coarse material alike toward the sea. These actions are always going on. Are they always equally balanced, or are there periods when the forces of elevation are more active, the forces of degradation not so powerful, as against other times in which the forces of degradation alone are at work? If there is inequality in the balance and struggle of these contending forces, the great periods or acts in the geologic drama might thus be marked off as Chamberlin suggests.
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